Eastman Tritan™ copolyester provides excellent gloss and picks up mold finish very well. When using it in a mold designed for other plastics, however, there are factors you need to consider in order to achieve success.
Here are some guidelines for polishing Eastman Tritan™ copolyester:
- Specify SPI mold finish standards.
- Specify surfaces smooth enough to minimize ejection force.
- Specify final polish in the direction of draw to minimize scuffing.
- Add a light 320 dry grit blasting (SPI B3 finish) to drafted walls to reduce the possibility of a vacuum forming during ejection.
It's important to keep in mind that surfaces polished smoother than required for ejection add to mold cost. 低い位置あるいは抜き勾配のない部分で真空箇所が発生している場合、過剰に研磨された表面はほとんどのケースで離型を悪くします。一方、真空箇所がない場合は通常、表面の研磨で取り出しやすくなります。
You may encounter the risk of surface defects when polishing Eastman Tritan™ copolyester. To prevent them, remember these tips:
- Pay attention to the part design if a surface finish is expected on the final product. Abrupt changes in wall thickness, relatively thick sections, or heavy ribs can cause variations in surface gloss. Uniform mold temperatures are needed to ensure that the texture is even throughout the pattern.
- To achieve a higher matte finish, double or triple the texture etching.
- If weld lines are visible on the final product, one alternative is to move the gate positions so that the weld line is formed in a less visible place. If this is not possible, apply a rounded texture pattern to help hide the blemish.
- If the material you are molding is expected to have poor scratch resistance, use a rounded texture pattern to hide potential marks.
Every combination of existing mold properties and molding requirements is different. Tritan™ experts can review your polishing and texturing methods and help you evaluate the results of optimizing your old mold.
Each medical grade of Eastman Tritan™ copolyester offers a different combination of superior strengths that help optimize performance for specific medical applications. Depending on the needs of your device, you may need a clear or opaque material.
If your device is clear, such as fluid management and IV components, renal devices, or dialyzer housings, you’ll need a material with the following properties:
- Glasslike clarity for an unobstructed view of fluid levels, foreign substances, and the ability to detect air bubbles, clots, or blood leakage during treatment
- Durability and toughness to withstand the applied stress of handling, connecting, and fabricating
- Chemical resistance to endure aggressive cleaning and bonding agents as well as harsh drugs and their carriers
- Color stability after sterilization
- Biocompatibility with FDA/ISO 10993 and USP Class VI biological evaluation
- Heat resistance
- Specific rigidity requirements to comply with ISO 80369 (required in some connectors)
Eastman Tritan™ MX711, MX731, or MX811 copolyesters are clear material grades that meet these needs. They have high impact strength and toughness, excellent clarity, elevated chemical resistance, and good color stabilization upon sterilization.
Opaque medical housings and hardware require a different set of properties than clear applications. For an opaque application, you'll need a material that can deliver:
- Superior chemical resistance and impact strength to resist cracking, breaking, and premature device failure during rigorous daily use and disinfection
- Ability to retain finish after repeated applications of bleach and alcohol
- Color stability and matching of brand standards
- Less noise in devices where sound reduction is valued
- Processability—moldability and resistance to solvents
- Flame resistance
Find more information here about the advantages of Tritan for a wide range of medical applications. Eastman also provides technical expertise and support to help determine your best material option. Contact us for help bringing your product to market quickly and efficiently.
The success of Eastman Tritan™ copolyester—especially in medical devices—makes more brand owners want to try it. One challenge to even
greater success has been how to use molds designed for other plastics. Sometimes it works fine - sometimes not so much.
Successful molding of any polymer depends on the ability to fill the part, cool the mold, and "freeze" the melted resin. Failure to do
so can cause sticking and ejection molding difficulty—which can limit the number of parts per hour and the quality of the parts.
Since most competitive materials freeze off at a higher temperature than Tritan, the mold may now need to cool more efficiently and
quickly than the original design. Engineering solutions that are straightforward when a customer builds a new mold for a different resin
can become challenges when a molder wants to produce high-quality Tritan parts by optimizing “this old mold.”
- The suggested mold temperature for running Tritan is 38°–66°C (100°–150°F).
- Uniform temperature throughout the mold helps ensure even heat transfer from both wall surfaces, which decreases residual stress and warpage and reduces cycle time. When optimizing an existing mold, keep this in mind so upgrades do not upset existing dynamics.
- Tower water may be adequate, but we strongly recommend using chillers to ensure a proper supply of cool water to the molds. Properly sized pumps and supply lines are also critical.
Here are the most common actions required when optimizing existing molds to run Tritan.
- Consider the theramal conductivity of the mold material. This is one variable you can't change, so it's important to factor it into all changes you can make.
- Evaluate the current cooling line layout, and make sure all changes are made to achieve uniform cooling.
- Make sure you have a turbulent water flow in the lines-laminar flow only has ½ the cooling efficiency of turbulent flow. Changing flow dynamics may be more cost-effective than changing diameter of the coolant channel.
- Use baffles or bubblers to achieve proper core cooling.
- Consider circular cooling channels around the cavity and core inserts.
- Injection molding gates typically have the highest heat load in an injection mold
- Increased cooling efficiency here can pay big dividends.
- Consider adding cooling lines adjacent to sprues.
- Spiral cooling sprue inserts or high-conductivity sprue bushings can be cost-effective retrofits.
- Poor venting can result in incomplete fill, increased pressure heat, and bum marks.
No old mold is typical
Every combination of existing mold properties and molding requirements is different. Because your needs are unique, we recommend involving Eastman as early in the planning as possible. Contact the Tritan Experts.
Eastman can review your tooling drawings and help you plan for uniform mold cooling. The Tritan experts can also help you evaluate the results of optimizing your old mold.
In general, small thick-walled parts made with Eastman Tritan™ copolyester can be ultrasonically welded by
following the welder’s recommendations for other amorphous thermoplastics.
Like all ultrasonic welding applications, those involving Tritan may require some optimization to achieve
successful welds. In particular, larger diameter, thin-walled parts may require
additional consideration of part design and welding operation.
Tips for ultrasonic welding of thin-walled parts
microns for 15 kHz of amplitude to weld (converter x booster x horn).
• Power output may vary depending on part size and wall thickness—2000- to 4000-watt generator is
energy mode capability. Feedback recording is critical for optimizing weld strength.
• Additional weld joint designs may be necessary for a given application. Details on specific weld joint options are available from Brett Jones and his team.
• A vibrating part leads to both poor energy transfer and the potential for the part to move out of alignment.
• Stabilization should be accomplished with a split-fixture clamping system (modified toggle clamp), which:
- Prevents movement of the outer section of the part
- Accommodates faster cycle time
- Prevents part marring
- Fixture devices can be fabricated using any rigid material, such as aluminum.
The coefficient of friction of copolyesters such as Eastman Tritan™ copolyester is at its highest near the heat deflection temperature (HDT) of the material-and competitive materials generally freeze at a higher temperature than Tritan. Keep this in mind if you're repurposing a mold that was originally designed for the cooling temperature of another plastic. Parts molded with Tritan must be adequately cooled to withstand ejection forces during demolding.
Three mold design and maintenance factors can also help ensure a clean and efficient release:
Draft—Part design features with minimal draft, such as long cores and deep ribs, often result in high ejection forces. The Eastman Design Services team recommends that all wall surfaces have a minimum draft angle of 1° in the direction of draw.
Polish—Polishing mold cavity features in the direction of draw will reduce the coefficient of friction and result in lower ejection forces required.
Mold steel coatings—Several mold steel coatings have been successfully used to reduce the coefficient of friction and required ejection force. Ask Eastman Design Services for a description of these coatings.
NOTE: A textured surface may affect all three factors and should be considered when you're designing the mold. Working with Eastman Design Services early in the process can help reduce frustration and cost later.